四川省成都市树德中学2021-2022学年高三上学期10月阶段性测试理综试题.pdf

1、 2021-10 17 201910 150 300 H-1 C-12 Cu-64 Au-197 126 216126 136 1 A B C D 21HgCl2ATP2 AHgCl2 BpH C D 3 A BCO2 C D 4 A B C D 5 A BNADPH C15%100%C3 DC18O218O2H218OH218O18O2 631 A3F3 BCO2 C D 15NDNA14N14N15N 7 A B()()Fe3O4 C D AA BB CC DD 8NA A16.8LCH4CH3Cl0.75NA B1.05molNa2O2CO2SO21.05 NA C78gH23NA D2

2、2.4LO2SO2SO32NA 2021-10 27 9()WYZWYZXWXNe AWXW BX-2 CZ3YX3 DWXW 10 A B NO C DCO2 112020 A B C D 12acBPH+OH-AX B Cxmolxmol H2O DXaX 13c(CH3COOH)c(CH3COO)0.1 molL-1 lgc(CH3COOH)lgc(CH3COO)lgc(H+)lgc(OH)PHKaCH3COOHKhCH3COO AN c(CH3COOH)=c(CH3COO)BPpOHlgKh COP CH3COO D:8614181921630 14 A B C D 15OPPQPQP

3、QOPO3060 AP BP CQ DQ 2021-10 37 16 A B C D 17500km36000kmGRgT A B C D 18m=1kg330v=10 3 m/s10m/s2 A B C5 3 mg D()321:8 19MN A BM CMM DM 20a=37M=2.0kgABCm=1kgACBABBC.C26NFABC.g10m/s2 AFF5N BFF18N CFF DFF 21m1=1kgm2=2kg0.4m1g.1.0m;1.4m.g=10m/s2.As Bs CF F24N DF F20N 22323338 226GF1F2OFO 1_ AF1F2 B CO D

4、 2FF1F2GO_FF 3F1F290OF2F1F2F1_ AF1 F2 BF1 F2 CF1 F2 DF1 F2 2021-10 47 239M50Hz610gm 1 i.6_ ii.15a iii.ii iv.16nn11an 229.80m/sg _ A B C D24mg 4a_2m/s _Mmgan11anM 2412ABCBCAC12 mAB53ACA2.1 mMPPG(P)GMCPGsin530.8cos530.6g=10m/s2(1)PCGMh1(6)(2)PABGMh2(6)2520M=1kgm=1kg=45F1=5N3sF12.25sF2=2N1=0.42=0.1g=10

5、m/s2 10-3s6 2x8 36 2614(Co2O3)(CoO(OH)CoCO3Cu2(OH)2CO3SiO2FeMgCa)(Co2O3)Ksp(FeS)6.310 18Ksp(CuS)6.310 36Ksp(CaF2)5.310 9Ksp(MgF2)5.210 11 1 ()21SiO2 CoO(OH)Na2SO3 3 FeSCuS K 4INaClO3 IIINa2CO3 5CoC2O42H2OCo2O3 2021-10 57 2714I.(SOCl2)1ZnCl2xH2OZnCl2 A BCDE 2ZnCl2Na2CO3pH5.549.54ZnCO3 (Zn21.0 mol/L)a

6、.ZnCl2Na2CO3 b.ZnCl2Na2CO3 c.Na2CO3ZnCl2 II.(SO2Cl2)Cl2SO2 SO2(g)Cl2(g)SO2Cl2(l)H97.3 kJmol 1()3 4 5?6(ClSO3H)2ClSO3HSO2Cl2H2SO4 281520302060 1CO2 CO2(g)+3H2(g)CH3OH(g)+H2O(g)H149.58 kJmol-1 CO2(g)+H2(g)CO(g)+H2O(g)H2 CO(g)+2H2(g)CH3OH(g)H390.77kJmol-1 2=kJmol-1 2II a.v(CO)=v(H2O)b.c.d.n(CO2)/n(H2O)

7、3CO2 ACO2M1 B CMN DCO2 42L3molH21molCO2150kpat minv(CH3OH)_ kpamin-1(t)Kp=5LiCO2 LiCO2CO24 I.2CO2+2e-=C2O42-II.C2O42-=CO2CO22-III._ IV CO32-2Li=Li2CO3 CO2 CO2(CH3CH2CH2OH)_ 299 1_ 2Ca2+3 2021-10 67 3010NaHSO3Z(T)(W 24 h8 hATP 1(W)24 hABA8 hB AB 2Z NaHSO3 3 319ARCRNARNAmiR-223HRCRHRCRmiR-223miR-223 1

8、miR-223_ 2miR-122 P RNAABmiR-122 miR-122 miR-122 miR-122 /3_ _ 3211F1F1F2=9:3:4 1_ 2F1_F2_ 3F2 _ A/aB/b _AABB _AABb 333-315 343-415 15MNxA1/3Hz2mx6mx0t_122435130 A Bx=3m Ct=0.5sx=10m D2stx=1mA E3st5 210RABA45A30BABc i ii30BAh.2021-10 77 35315 20201217159HONAlSCdZnTiCuAuCr 1(Zn)(Cd)CdCd()_ZnCuZnCu 2S

9、OSO3289.8KSO3S_ 3Cr2O 27ymol_ 4Al2O3_ 5CuAuAu_CuAuCuAuZnS()_apmNA gcm-3()36515 MM OH 1A_B 2F_FG_ 3GM 4QDQ ()5 NH2CHO 52-()37115 1_ 20_ 3GB5750-2006_ 383 2021-10 87 201910 1-6BAACCB 29.9 1 1 2 3 30.10 1Z(T)NaHSO3 21 1 1 (1)31 1 31.9 1miR-223mRNA1 HRCR 2 1 3DNA1 1 32.11 11 1 2=1:1:2 =1:1 3 1 =3:1=3:1

10、37.15 1 2 1 3 7.DABCD 8.AACH3ClCH2Cl2CHCl3CCl4CH3Cl0.75 NAB.Na2O2CO2SO2Na2O2 SO22.1 NAC78g1molD.9.CWYZHW+2X2Z1ZHWIIAXVIAWXNeWMgXOWYZXY6-2-1=3YHMgYBWMgXOYBZH A2WX BO-2-1 CH3BO3 D MgO 10.B A.B.NOO2C.CuD.CO2 11.B A(-OH)-NH-CO-B-NH-CO-OHC 612122C31233OCD.-OH 12.CBPH+OHY2H+2e=H2X4OH-4e=O22ONa+cBPOH-NaOHc

11、Cl-aBPH+ac1mol2molXa 13.B PHCH3COOHpH=71lgc(CH3COO)pH2lgc(H+)pH3lgc(OH)pH4lgc(CH3COOH)pH A.Nc CH3COOH=c(CH3COO)B.PKh=c(OH)c(CH3COOH)/c(CH3COO)c(CH3COOH3COO)c(OHCOPc(CH3COO)D.Ka=c(CH3COO-)c(H+)/c(CH3COOH)c(H+)=Kac(CH3COOH)/c(CH3COO)=26.14 11 2CaSO4 1 2CoO(OH)+SO32-+4H+=2Co2+SO42-+3H2O2 3FeS(s)+Cu2+(a

12、q)Fe2+(aq)+CuS(s)2 1.010182 4 2 Co2+(Co2+)2 54CoC2O42H2O+3O22Co2O3+8CO2+8H2O 2 1 2 CoO(OH)Na2SO3CO2+SO42-3s K=Fe2+/Cu2+=Ksp(FeS)/Ksp(CuS)=1.01018 2021-10 97 4 5 27.142 1 DEC2 2c 3(SO2Cl2)4 5 6 1 EDCSOCl2C 2pH5.549.54PH5.54 3(SO2Cl2)4 5 6SO2Cl2 28.152 1+41.19 2bcd 3CD 418.75/t 3 5 2CO22-+CO2=2CO32-+C

13、 3CO2+18e+13H2O=CH3CH2CH2OH+18OH 1-2a.b.cd.3A.CO2CO2M B.CO2 CMNK D.CO2 4CO2+3H2CH3OH+H2O mol 1 3 0 0 mol 0.5 1.5 0.5 0.5 mol 0.5 1.5 0.5 0.5 P=112.5kpan(CH3OH)=0.5molP(CH3OH)=18.75kpaV(CH3OH)=18.75t kPa/min 5LiCO2LiCO24Li+3CO2=2Li2CO3+C3CO2+4Li+4e=2Li2CO3+C2CO22-+CO2=2CO32-+C CO2+4C-2()C3CO2+18e+13H

14、2O=CH3CH2CH2OH+18OH 35.152 1 1Zn3d104s2 2sp3 341 4Al2O3Al3+O2-512 AuCu3H8 197+364/(2 a10-10)3NA(1)(Zn)(Cd)CdCd48Cd()Zn3d104s2(2)S4sp3(3)11Cr2O 271mol8mol4mol2mol8mol4:1(4)Al2O3Al3+O2-(5)CuAuAuCuAu8Au12AuCuH24AuCu3H8 1mol1mol197+364gx=2 a10-10 cm 1mol(2a10-10)3NAcm3=197+364/(a10-10)3NA g/cm3 2021-10

15、107 36.152 1 BB 2 3 410(5)3 14.A 15.A 16.C 17.D 18.D 19.BC 20.AC 21.AC 22.CD F B 23.1 2CD 0.820 1161()Mmanmgg 24.(12)(1)(4)()Pv12gh1Px1v1t1y112gt21 ACAMh1y1 x12 h1(9.9h1)h14.95 m(2)(5)()PABD Pv22gh2 Px2v2t2y2vy22 t2vy2gt2 Dvy2v0tan 43v2x2tan AMh2y2 h22.7 m(3)()PB Pv32gh2 x3ACcot 9 my3ACAMh2 Px3v3t3y312gt23h29(1121)20 mh29(1121)20 mh2()25.20(1)m M (2)3s F1mMt m M =t=1.25s 5.25s t3 m =(3)F2a4a3 m M a3 M F2 34.1BDE 2i30451sinn2n ii7sinsinn045 Bsinsinn030 L BA