四川省树德中学2022届高三下学期开学考试理综试题.pdf

1、 16 2019 H1 C12 N14 O16 Na23 P31 S32 Fe-56 Co59 126 216126 136 1 A BDNA CK+D 2 A B C DDNA 3 A B C D 4BapoB48apoB100apoB100mRNACAAUAAapoB48RNA AapoB48apoB100 BRNA CapoB48apoB100 DapoB48apoB100mRNADNA 5GAABA 1 1 2 2 MS MS MS+GA MS+ABA MS MS+ABA A1GA B2ABA CABA DGAABA 6Bb1040100 A B100 Bb16%C D36%72220

2、2224 A B C D 8NA ApH=1HClHClNA B0.3molNO2H2O2.24LNO C6.4gS8SS0.2NA D1LpH=40.1molL 1K2Cr2O7Cr2O70.1NA 9WXYZMQW1QZ8 AW3MZ4Q BZYQ CQMYZ DQ2Z3X2Z4 10.PCBO4+2M()M A B C9()D 11 A SiO2 CSi B pH1 molL 1 CH3COONH40.1 molL 1 CH3COONH4pH pH7 CH3COONH4 C KIKSCN KIFeCl3 D 4 mL 0.01 molL 1 KMnO44 mL 0.1 molL 1 KM

3、nO4SO2 0.1 molL 1 KMnO4 26 12N2O5 AcN2O4-2e-+H2O=N2O5+2H+B2mol2molN2O51molH2SO4 C1molSO22molH+ba DbO2+4e-+2H2O=4OH-130.1 molL 1NaOH16.00 mLHANaOHpH(plgaaKK100.48=3HAHCN)AHA10-5 Bbc(A-)+c(OH-)=c(Na+)+c(H+)Cc c(A-)c(HA)c(H+)c(OH-)DHAHCNpHNaOH:8614181921630 14OAO1BO21212CAB AA BB C D 152021515.MN280()5

4、.9mNv NrRG AMmv BM423 CMN DNv2r 16()m2 kg()x1 mv01.5 m/sx0.05Ep()PABx1 mAB(03)(30)g10 m/s2 Ax3 m B Cx3 m Dx4 m 17ABAABBBABB AAB BB C DAB 182 kgM4 N1 kgmMm0.5MFFMxF30.5x(FN xm)g10 m/s2 Am4 m/s2 Bm5 m/s2 Cm48 J DM24 m12 Ns 19n1n231MNabcb4 16 Wac32 W Ac8 W Ba0.5 A Cb8 V DMN24 V 20mR0.7 mABBABL2.5 mmv06

5、 m/s(g10 m/s2)AAB5 m/s BAB1.8 m CAB0.5 DAB0.50.35 m 36 21MNPQdR1R2RO1O2BmdO1O2FtO1O2FNQR ABdFtm B3FtR2B2d2 CF2t22m DR1F2t212m 22323338 2251 O O POx m mxx1m2 1Ox_ AL0BPLC DL12g2P_(2ab(1)2310SRR1R1Er(1 1R1 SRR0 10 acU1 abU2_V R1R1_(U1U2R0)R1 2Er R13.1 a_(bcRU RU 1U1R1U1R E_Vr)_(241237v05 m/sm1.5 kgAAh

6、2.4 m10.520.2g10 m/s2 1E 22nE2n2n1E2n1E2nE2n1(n 3s R1RS0.300v 46 2520 xOy(xy)Btmqt0 xOT0B0K qsin 370.6cos 370.8 1 025T0 2yT0m 3x(3d4d)Dv 2615(NaH2PO2)(A)PH3(H3PO2)1a_ 2A 3K1N2_ 4PH3 5CC_ NaH2PO2(NaH2PO2100 g667 g)6m g250 mL_(25.00 mL 0.01 molL 1KMnO4(PO34 )V1 mL KMnO4_ 2714 LiCoO2-33sp3Al(OH)=1.0 10

7、K 1 2LiCoO2 3-5-11.0 10 mol LAl pH_ 4P2O4_()aP2O4 b c d 5P2O4P2O4 6CoC2O418.3g CoC2O42H2O 28(14)(DME)231CO g+2HgCH OH gH -1333222CH OH gCH OCHg+H O gH=-23kJ mol 13CH OH g2Hg-1-1763.7kJ mol 285.8kJ mol,1mol44kJ33CH OCHg_ Ea()-1akJ molEa()_kJ/mol 2v=kc(CO)c2(H2)v=kc(CH3OH)kkkk1H _0(A Bx+1.5 x-1.5T1K=_

8、 3100MPa22mol CO 4mol H2L 10min-12c H=0.8mol L-12c H O=0.15mol Lv(CO)=_1-1mol LminIKp=_-2MPa(Kp=)4(CH3O)2CO _ B_(2 56 299 NaHCO3 1_HATP_ 2_ 308 1 2_ 3110 B 11220_BATP/ADPATPK+Ca2+B_ 23 ()3AB AB _ 3212 XYE/eXF/fFEF 1_ 21/16_F1_ 3EeXFXfEeXFY_XXY_ 66 333-315 343-415 15xt0t0.05 s80 cm/sx ()t0.20 sx3 cm

9、cm 210CAB75ROPACPC62 RMPAC30ACOcsin75624sin15624(i)n(ii)t 35315 1_ 2Cr_NH3HNH107.3Zn(NH3)62+HNH_107.3 3Ni2+Ni2+_ 4r(Fe2+)61pm r(Co2+)65pmFeCO3CoCO3FeCO3CoCO3_ 5NiNiaONaCla0.88NiNi2Ni3Ni2Ni3_ 6NFea nmc nmNA 3()36515 G RCOOH+H2O 1_ 2F_ 3_ 4NEMFXX_ 5D_ a.b.3221 6_()37115 1_ 210g90mL0.1mL,104789195_ 3_

10、4 _ _ 38315 76 2019 1-6 A C B B C D 29.(29)1 2(1)HATP 30.(8)12 1 2DC1 1 18%(1 2 31.(10)1B B5-102 1 21 1 B2 3AB 3 32.(212)19 eeXfYeeXfXf 2EeXFXf 3/8 3=8:4:3:1 XfXf 37.(215)1 28.8106 3 4(1)(4 7-13BCCACBD 26.152 11 2P43NaOH3H2O=3NaH2PO2PH3 3PH3 4K1N2 5NaClNaH2PO2 61 30 s1 1.1V1m%27.142 1Li+22LiCoO2+6H+

11、2-3SO=2Li+2Co2+2-4SO+3H2O 3 34.7 4abc 5 6 3CoC2O4+2O2Co3O4+6CO2 3 28142 1 -1kJ1460.4mol 1 a+23 2 1 1000 3 0.06 42CH3OH+CO-2e-=(CH3O)2CO+2H+Pb 35.(152)1 1 2sds 3sp2sp3 NOC 42+Fe2+CoFeOCoO3FeCO3CoCO 58:3 6 36.151 1 2 3+H2O 2 86 425C H OH32CH CH OH2 5 42 6(4 14 15 16 17 18 19 20 21 A B D C C AC AD BD 2

12、2.(5)BC(1)bgcos2 4asin(1)bcos2 4Lsin(2)23(10)(1)4.3(1)U1U2U2R0(1)b(1)10(2)0.90(2)(2)24.(12)(1)(4)x1hsin374 m mg(sin371cos37)x112mv210v14 m/s t12 v12g4 s EWf2mgv0t160 J(2)(4)2nmg(sin371cos37)x2n0E2n2n1mg(sin371cos37)x2nE2n 10 E2nE2n 15(3)(4)smgh1mgcos37ssh1cos376 m 25.(20)(1)(4)T23B0q2T3 fmaf3B0qvav2

13、R2R3(2)(8)Bvqmv2RRmvBq R1mv3B0qR2mv2B0q O1O2Csin R2R1R237 025T014336023B0q25T0m T0m143236K(3)(8)tan ADCD4353 025T0t110636023B0q53270B0q 25T0T0t1t223 t253180B0q10636022B0q 025T025T0T0106 x2R1sin 532R2sin 53 5dN x(N12 v154N(N12 34.34(15)(1)(5)(2)3(3)(2)(10)(i)(5)i9060r nsin isin r POCRsin(90r)PCsin(75r)PC62 Rr45n62(ii)(5)POCRsin(90r)OPsin(9075)OP312R PtOPRv ncv t(63 2)R4c(t(3(23)6)R2c)